Silicon Carbide Nanotube Synthesized

Carbon nanotubes (CNTs) have generated a great deal of scientific and commercial interest because of the countless envisioned applications that stem from their extraordinary materials properties. Included among these properties are high mechanical strength (tensile and modulus), high thermal conductivity, and electrical properties that make different forms of single-walled CNTs either conducting or semiconducting, and therefore, suitable for making ultraminiature, high-performance CNT-based electronics, sensors, and actuators. Among the limitations for CNTs is their inability to survive in high-temperature, harsh-environment applications. Silicon carbon nanotubes (SiCNTs) are being developed for their superior material properties under such conditions. For example, SiC is stable in regards to oxidation in air to temperatures exceeding 1000 C, whereas carbon-based materials are limited to 600 C. The high-temperature stability of SiCNTs is envisioned to enable high-temperature, harsh-environment nanofiber- and nanotube-reinforced ceramics. In addition, single-crystal SiC-based semiconductors are being developed for hightemperature, high-power electronics, and by analogy to CNTs with silicon semiconductors, SiCNTs with single-crystal SiC-based semiconductors may allow high-temperature harsh-environment nanoelectronics, nanosensors, and nanoactuators to be realized. Another challenge in CNT development is the difficulty of chemically modifying the tube walls, which are composed of chemically stable graphene sheets. The chemical substitution of the CNTs walls will be necessary for nanotube self-assembly and biological- and chemical-sensing applications. SiCNTs are expected to have a different multiple-bilayer wall structure, allowing the surface Si atoms to be functionalized readily with molecules that will allow SiCNTs to undergo self-assembly and be compatible with a variety of materials (for biotechnology applications and high-performance fiber-reinforced ceramics)

Hausarztforschung in der Schweiz holt auf

An der 13. Fortbildungstagung des Kollegiums für Hausarztmedizin (KHM) wurde zum fünften Mal der KHM-Forschungspreis Hausarztmedizin verliehen, dieses Jahr im Rahmen eines eigenständigen Symposium

New and extended parameterization of the thermodynamic model AIOMFAC: calculation of activity coefficients for organic-inorganic mixtures containing carboxyl, hydroxyl, carbonyl, ether, ester, alkenyl, alkyl, and aromatic functional groups

We present a new and considerably extended parameterization of the thermodynamic activity coefficient model AIOMFAC (Aerosol Inorganic-Organic Mixtures Functional groups Activity Coefficients) at room temperature. AIOMFAC combines a Pitzer-like electrolyte solution model with a UNIFAC-based group-contribution approach and explicitly accounts for interactions between organic functional groups and inorganic ions. Such interactions constitute the salt-effect, may cause liquid-liquid phase separation, and affect the gas-particle partitioning of aerosols. The previous AIOMFAC version was parameterized for alkyl and hydroxyl functional groups of alcohols and polyols. With the goal to describe a wide variety of organic compounds found in atmospheric aerosols, we extend here the parameterization of AIOMFAC to include the functional groups carboxyl, hydroxyl, ketone, aldehyde, ether, ester, alkenyl, alkyl, aromatic carbon-alcohol, and aromatic hydrocarbon. Thermodynamic equilibrium data of organic-inorganic systems from the literature are critically assessed and complemented with new measurements to establish a comprehensive database. The database is used to determine simultaneously the AIOMFAC parameters describing interactions of organic functional groups with the ions H^+, Li^+, Na^+, K^+, NH_(4)^+, Mg^(2+), Ca^(2+), Cl^−, Br^−, NO_(3)^−, HSO_(4)^−, and SO_(4)^(2−). Detailed descriptions of different types of thermodynamic data, such as vapor-liquid, solid-liquid, and liquid-liquid equilibria, and their use for the model parameterization are provided. Issues regarding deficiencies of the database, types and uncertainties of experimental data, and limitations of the model, are discussed. The challenging parameter optimization problem is solved with a novel combination of powerful global minimization algorithms. A number of exemplary calculations for systems containing atmospherically relevant aerosol components are shown. Amongst others, we discuss aqueous mixtures of ammonium sulfate with dicarboxylic acids and with levoglucosan. Overall, the new parameterization of AIOMFAC agrees well with a large number of experimental datasets. However, due to various reasons, for certain mixtures important deviations can occur. The new parameterization makes AIOMFAC a versatile thermodynamic tool. It enables the calculation of activity coefficients of thousands of different organic compounds in organic-inorganic mixtures of numerous components. Models based on AIOMFAC can be used to compute deliquescence relative humidities, liquid-liquid phase separations, and gas-particle partitioning of multicomponent mixtures of relevance for atmospheric chemistry or in other scientific fields

Prevalence of non-functional overreaching and the overtraining syndrome in Swiss elite athletes

Objectives: Fatigue and unaccountable underperformance are common for athletes, but there is a lack of empirical data regarding the prevalence of non-functional overreaching (NFOR) and the overtraining syndrome (OTS). Using the overtraining definition of the European College of Sport Science (ECSS), the present study aimed to explore the prevalence, symptoms and associated factors of NFOR/OTS across Swiss elite athletes in various sports. Method: 139 Swiss elite athletes (63 males and 76 females, Mage = 23.6, SDage = 5.6 y) from 26 different sports completed a1 7-item online survey about underperformance and symptoms of NFOR/OTS. 95% of the sample represented Switzerland in their sport. Athletes were classified as NFOR/ OTS by according to the overtraining definition of the ECSS. Data were analysed using Mann-Whitney U nonparametric tests and ANOVAs. Results: 9% of the athletes were classified as OTS and 21% as NFOR at least once in their career. The prevalence was significantly higher in medium-physical demand sports than in low-physical demand sports (p = .02). There were no significant differences in the NFOR/OTS prevalence between individual and team sports and female and male athletes. Competition level and training load had also no significant influence on the NFOR/OTS prevalence, although low-physical demand sports trained significantly less than medium- and high-physical demand sports. Injury/illness, loss of weight and sleep disturbance rates were significantly higher in the NFOR/OTS group. More than 70% of the NFOR/OTS athletes reported loss of motivation and emotional disturbances. Conclusions: The NFOR/OTS career prevalence rate of Swiss elite athletes can be estimated at approximately 30%. NFOR/ OTS is accompanied by biopsychosocial signs of maladjustment, e.g., emotional disturbances, loss of motivation, sleep disturbances, injury/illness and weight loss, but training load is not a predictor of NFOR/OT

Exergy analysis of a high-temperature-steam-driven, varied-pressure, humidification–dehumidification system coupled with reverse osmosis

In this study, exergy analysis of a novel desalination system is presented and discussed. The water desalination is carried out using combined humidification–dehumidification and reverse osmosis technologies. Six system performance parameters are examined: overall exergetic efficiency, equivalent electricity consumption, specific exergy destruction, specific exergy lost, and total true specific exergy lost, as well as the exergy destruction ratios of the main components. The total true specific exergy lost is a new parameter presented in this study. It is a function of summation of total the exergy destruction rate and loss per total mass flow rate of the total pure water produced. This parameter is found to be a useful parameter to assess the exergetic performance of the system considered. By contrast, use of overall exergetic efficiency as an assessment tool can result in misleading conclusions for such a desalination system and, hence, is not recommended. Furthermore, this study reveals that the highest exergy destruction occurs in the thermal vapor compressor, which accounts for 50% of the total exergy destruction of the system considered. This study, in addition, demonstrates that the specific exergy destruction of the dehumidifier and TVC are the parameters that most strongly affect the performance of the system.Center for Clean Water and Clean Energy at MIT and KFUP

Anti-Treponema pallidum IgA response as a potential diagnostic marker of syphilis

Objectives: Serological tests for syphilis detect mainly total Ig, IgM or IgG antibodies. We aimed to evaluate the specific IgA response in syphilis patients according to disease stage. Methods: A serum IgA-enzyme immunoassay was developed using commercially available microplates coated with recombinant treponemal antigens and an anti-IgA-conjugate. To define a cut-off, we used 91 syphilis positive and 136 negative sera previously defined by the rapid plasma reagin and the Treponema pallidum particle agglutination results. Then we determined the intra- and inter-assay precisions, diagnostic sensitivity according to the clinical stage (in 66, 55 and 42 sera from primary, secondary and latent syphilis patients, respectively) and specificity (in 211 sera from people with conditions different to syphilis). IgA values were further measured in 71 sera from patients with previously treated syphilis. Results: The newly developed IgA-enzyme immunoassay showed a good discrimination between negative and positive samples with intra- and inter-assay variation coefficients <20%. The sensitivity was 80.3% (95% CI, 70.0-90.6), 100.0% (95% CI, 99.1-100.0) and 95.2% (95% CI, 87.6-100.0) in primary, secondary and latent syphilis, respectively, and the specificity was 98.1% (95% CI, 96.0-100.0). Further, IgA values were negative in 61.3% (38/62) of patients with previously treated syphilis. Discussion: Our findings suggest serum IgA as a sensitive and specific marker of syphilis and its detection could be used as a screening assay for active infection. Further evaluation is needed in prospective longitudinal field studies

On Real Fluid Flow Over Yawed Circular Cylinders

The equations for both the boundary layer and the outer potential flow over a yawed cylinder can be resolved into equations for the crosswise and spanwise velocity components. These components of the boundary layer are evaluated using Sears’ method, and the separation point is found to be uninfluenced by the yaw angle. The potential-flow solutions for the spanwise and crosswise flows are added together to determine vortex patterns behind the cylinder. The approximate direct dependence of the Strouhal number upon the cosine of the yaw angle and/or the drag coefficient upon the square of the cosine, are verified. Experimental determinations of the Strouhal number and visualization of the flow pattern are consistent with the analysis

Effect of mass extractions and injections on the performance of a fixed-size humidification–dehumidification desalination system

The impact of mass extractions and injections as a method for increasing the energetic performance of fixed-size humidification–dehumidification desalination systems is examined. Whereas previous studies of this problem have been restricted to thermodynamic models, the use of a more complete model that includes transport provides the ability to quantify the impact of mass extractions/injections on a realizable, fixed-size system. For a closed air, open water cycle, the results show that a single water extraction from the dehumidifier to the humidifier increases the gained output ratio by up to 10%, with extractions higher in the cycle proving more effective. The sizing problem for the humidifier and dehumidifier under thermodynamically optimized conditions found in literature is also discussed, as is the impact of system size on overall performance of a system without extractions/injections. For a range of sizes, it is shown that a rough doubling of both dehumidifier and humidifier size results in a two- to three-fold increase in gained output ratio, with diminishing returns as the absolute sizes increase.Center for Clean Water and Clean Energy at MIT and KFUPM (Project R4-CW-08)Eni S.p.A. (Firm)MIT Martin Family Society of Fellows for Sustainabilit